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KMID : 1059519870310040364
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Journal of the Korean Chemical Society
1987 Volume.31 No. 4 p.364 ~ p.368
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Synthesis of Nucleophilic Adducts of thiols (VIII). Addition of Thioglycolic acid, Benzenethiol and Benzylmercaptan to β-Acetyl-β-benzoylstyrene Derivatives
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Ha Tae-Sung
Baek In-Sook
Seo Kih-Lim
Kim Tae-Rin
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Abstract
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The addition reactions of thioglycolic acid, benzenethiol and benzylmercaptan to β-acetyl-β-benzoylstyrene were investigated. β-Acetyl-β-benzoylstyrene derivatives easily underwent addition reactions with thioglycolic acid, benzenethiol, and benzylmercaptan to form five (2-acetyl-2-benzoyl-1-phenylethyl)thioglycolic acid derivatives (Ⅱa-Ⅱe), five (2-acetyl-2-benzoyl-1-phenylethyl)benzenethiol (Ⅲa-Ⅲe) derivatives and five (2-acetyl-2-benzoyl-1-phenylethyl)benzylmercaptan derivatives (Ⅳa-Ⅳe), respectively.
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